Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1506431 | Solid State Sciences | 2009 | 8 Pages |
Abstract
A detailed comparative study of the valence tautomeric interconversion of complexes 1–3 in three different environments is reported. The three environments are solid state (both crystalline and amorphous materials), solution and embedded into a polymeric matrix. The VT behavior of the three complexes strongly differs from one to the other, though no systematization can be established. In solution, different solvatational parameters seem to affect the equilibrium. However, such solvate effect cannot be translated either into the solid state or polymeric matrix, where the equilibrium is controlled by the vibrational relaxation of the network.
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Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Emi Evangelio, Clara Rodriguez-Blanco, Yannick Coppel, David N. Hendrickson, Jean Pascal Sutter, Javier Campo, Daniel Ruiz-Molina,