Article ID Journal Published Year Pages File Type
1506756 Solid State Sciences 2007 5 Pages PDF
Abstract

The new zinc silico-phenylphosphonate has been synthesised. The substitution of phosphorus by silicon induced a deficit of the positive charges that were balanced by cations located in the interlayer space. The XRD pattern exhibits a series of (00l) reflections corresponding to a lamellar structure. The SEM micrograph of this material shows a morphology similar to the one observed for clay minerals and especially smectites “gypsum-like morphology”. TEM images exhibit a rods' arrangement for the layered materials. Q4 sites were identified by 29Si solid state NMR measurement indicating a full polymerisation of the silica.

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Physical Sciences and Engineering Materials Science Ceramics and Composites
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