Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1506756 | Solid State Sciences | 2007 | 5 Pages |
Abstract
The new zinc silico-phenylphosphonate has been synthesised. The substitution of phosphorus by silicon induced a deficit of the positive charges that were balanced by cations located in the interlayer space. The XRD pattern exhibits a series of (00l) reflections corresponding to a lamellar structure. The SEM micrograph of this material shows a morphology similar to the one observed for clay minerals and especially smectites “gypsum-like morphology”. TEM images exhibit a rods' arrangement for the layered materials. Q4 sites were identified by 29Si solid state NMR measurement indicating a full polymerisation of the silica.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Maguy Jaber, Olivier Larlus, Jocelyne Miehe-Brendlé,