| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1506779 | Solid State Sciences | 2007 | 5 Pages |
Abstract
Two complex oxides of osmium, Ba2Fe0.92Os1.08O6 and Ba2Co0.77Os1.23O6, have been prepared as single crystals from molten potassium hydroxide. Both oxides crystallize in the hexagonal space group P63mc with a = 5.7403(1) Å and c = 14.0771(6) Å and a = 5.7745(2) Å and c = 14.0946(7) Å for Ba2Fe0.92Os1.08O6 and Ba2Co0.77Os1.23O6, respectively. The structure of these compounds is related to the 6H–BaTiO3 structure but exhibit mixed occupancy of both metals on the three crystallographically independent metal sites.
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Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
William R. Gemmill, Mark D. Smith, Hans-Conrad zur Loye,