| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1506921 | Solid State Sciences | 2006 | 6 Pages |
Abstract
A new layered aluminophosphate [Ni(C4N3H13)(C4N3H14)H2O][Al3P4O16] has been prepared from a hydrothermal system Al(i-PrO)3Ni(OAc)2H3PO4diethylenetriamineH2O, and characterized by single-crystal X-ray diffraction, ICP, CHN and TG analyses. Its structure is built up from the alternation of AlO4 and PO3(O) tetrahedra to from 4.6.8-net sheets stacked in an ABAB sequence. The nickel complex Ni(C4N3H13)(C4N3H14)H2O that is formed under hydrothermal conditions locates in the interlayer region and interacts with the inorganic sheets through H-bonds.
Keywords
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Physical Sciences and Engineering
Materials Science
Ceramics and Composites
![A new nickel complex-templated layered aluminophosphate [Ni(C4N3H13)(C4N3H14)H2O][Al3P4O16]](/preview/png/1506921.png "First Page Preview: A new nickel complex-templated layered aluminophosphate [Ni(C4N3H13)(C4N3H14)H2O][Al3P4O16]")
Authors
Mei Wang, Jiyang Li, Qinhe Pan, Jihong Yu, Xiaowei Song, Ruren Xu,