Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1515261 | Journal of Physics and Chemistry of Solids | 2016 | 11 Pages |
•NiO/RGO composites were synthesized under the different calcination temperatures.•Calcination temperature impacts capacitive properties as electrode.•NiO/RGO composites calcined at low temperature possess the excellent capacitive behaviors.•Crystallinity, component and surface defects play major role on capacitive character.
A series of NiO/RGO composites based on NiO nanoparticles anchored on layered RGO surfaces were proposed by the same hydrothermal method combined with different calcination temperatures (250, 300, 400 and 500 °C). The effects of calcination temperatures on the capacitive behaviors have been discussed by investigating the components, morphologies, surface conditions of the NiO/RGO composites. The specific capacitance values of NiO/RGO composites calcined at 250, 300, 400 and 500 °C are 950, 553, 375 and 205 F/g at the current density of 1 A/g and the corresponding capacitance retention are 91.3%, 83.9%, 71.9% and 67.3% after 1000 cycles at the current density of 10 A/g. The results suggest the calcination temperature plays an important role in the electrochemical performances of NiO/RGO composites and the electrochemical performances were deteriorated with the increasing calcination temperatures.
Graphical abstractNiO/RGO composites synthesized by hydrothermal method combined with the different calcination temperatures exhibit the excellent capacitive behaviors.Figure optionsDownload full-size imageDownload as PowerPoint slide