Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1515414 | Journal of Physics and Chemistry of Solids | 2015 | 5 Pages |
Abstract
The increasing demand for the high energy density of lithium-ion batteries gives rise to the development of larger particle sizes of the active electrode materials. 20 μm-sized Li(Co1âxLix)O2âδ agglomerates are synthesized via solid-state reactions with different nominal compositions (Li/Co=1.00, 1.02, and 1.05) at 1000 °C for 5 h in ambient air while suppressing the lithium vaporization. Careful inductively coupled plasma and iodometric measurements indicate the existence of tetravalent cobalt in the solid solutions (x>0). The decreasing ideal capacity with the increasing x value could cause the resulting initial capacities at under a quasi-equilibrium condition. The defect structure is also discussed in terms of the structural parameters calculated from Rietveld refinements of the high-energy synchrotron-radiation powder-diffraction data.
Related Topics
Physical Sciences and Engineering
Materials Science
Electronic, Optical and Magnetic Materials
Authors
Y. Mishima, T. Hojo, T. Nishio, A. Kajiyama, C. Moriyoshi, Y. Kuroiwa,