Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1515948 | Journal of Physics and Chemistry of Solids | 2014 | 6 Pages |
Abstract
Surface oxides on small (2-5 μm) copper metal particles can be removed by chemical reaction with tris(2,3-dibromopropyl) isocyanurate (TIC) in diethylene glycol mono-n-hexyl ether (DGHE) solution under mild conditions where metal particles are not damaged. Surface oxides convert to copper bromide species and subsequently dissolve into the solvent. It was found that resultant surface species are resistant to re-oxidation due to remaining surface bromides. This finding opens up a possibility to create microclines based on cheap copper nanoparticles.
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Authors
Shun Yokoyama, Hideyuki Takahashi, Takashi Itoh, Kenichi Motomiya, Kazuyuki Tohji,