Atmospheric-pressure metal–organic vapor-phase epitaxy of GaAsBi alloys on high-index GaAs substrates

•GaAsBi layers were grown on different oriented GaAs substrates by MOVPE.•GaAsBi growth rate is particularly lower on (115)A GaAs layer.•The substrate orientation has a significant effect on Bi content and strain relaxation.

We investigated the growth characteristics and properties of GaAsBi layers grown by atmospheric-pressure metal–organic vapor-phase epitaxy on different GaAs substrate orientations. The surface morphology of GaAsBi alloys was investigated by means of scanning electron microscopy. The structural and optical properties of the alloys were examined using high-resolution X-ray diffraction (HRXRD) and photoreflectance spectroscopy, respectively. HRXRD results show that the GaAsBi growth rate was significantly lower on (1 1 5)A than on (0 0 1), (1 1 1)A and (1 1 4)A GaAs. The highest Bi content was obtained for GaAsBi layers grown on (1 1 5)A GaAs substrates.