Synthesis and characterization of the efficient visible-light-induced photocatalyst AgBr and its photodegradation activity

AgBr photocatalysts were prepared with the 1-hexadecyl-3-methylimidazolium bromide ([C16mim]Br) reactable ionic liquid at different temperatures by one-step hydrothermal method, in which the ionic liquid acted as a precursor and a template to control the size of AgBr crystal. The photocatalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), the Brunauer–Emmett–Teller (BET) surface area and diffuse reflectance spectroscopy (DRS). Methyl orange (MO) dye was chosen as a model pollutant to investigate the photocatalytic activity and the stability of the samples under visible light irradiation. The results indicated that the AgBr photocatalysts showed high efficiency in the degradation of MO under visible light irradiation. The kinetic property of the reaction followed the first-order reaction model. During the photocatalytic degradation reaction, AgBr was transformed to the Ag0/AgBr composite. However, the photocatalytic efficiency was still high and the photocatalytic activity was stable. The possible photocatalytic mechanism of the photocatalysts was also eventually proposed.

► The ionic liquid acted as a precursor and template in the synthesis of AgBr. ► The size and light absorption ability of AgBr affected the photocatalytic activity. ► AgBr photocatalyst showed high and good stable efficiency after five cycles.