Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1517163 | Journal of Physics and Chemistry of Solids | 2010 | 5 Pages |
Abstract
The antiferroelectric material Cs2Nb4O11 transforms at 165 °C from a low-temperature, antiferroelectric phase in space group Pnna to a high-temperature, paraelectric phase in space group Imma; the latter structure has been determined by single-crystal X-ray diffraction. The high-temperature lattice is comprised of niobium-centered tetrahedra and octahedra connected through shared vertices and edges; cesium atoms occupy channels afforded by the three-dimensional polyhedral network. Calculated band structures for both phases predict a bandgap of 3.1–3.2 eV, which is similar to that found experimentally through photoluminescence. The calculated band structure is also conducive to its observed photocatalytic properties.
Keywords
Related Topics
Physical Sciences and Engineering
Materials Science
Electronic, Optical and Magnetic Materials
Authors
Robert W. Smith, Guangfu Luo, Wai-Ning Mei,