Article ID Journal Published Year Pages File Type
1517848 Journal of Physics and Chemistry of Solids 2007 5 Pages PDF
Abstract

We report 51V NMR experiments in the metallic phase of the quasi-one-dimensional (1D) conductor ββ-Sr0.33V2O5Sr0.33V2O5. The Knight shift and the quadrupole splitting of all six vanadium sites were determined as a function of the direction of magnetic field perpendicular to the conducting bb-axis. Magnetic properties of the three 1D structural units are remarkably heterogeneous. In particular, the V2 ladder unit shows pronounced charge disproportionation among the two (V2a and V2b) sites. At one of these sites, the absolute value of the Knight shift and 1/(T1T)1/(T1T) increase steeply with decreasing temperature, suggesting development of ferromagnetic correlation.

Related Topics
Physical Sciences and Engineering Materials Science Electronic, Optical and Magnetic Materials
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