| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1521073 | Materials Chemistry and Physics | 2015 | 10 Pages |
•The characteristics of precipitation and coarsening of Laves-phase were determined.•The matrix depletion of W and Mo due to Laves-phase precipitation was quantified.•The effect of precipitated Laves-phase on the hardness was evaluated.
Long term precipitation and coarsening of Laves-phase in tungsten strengthened 9% Cr steel under thermal aging at 923 K was investigated and reported in this paper. It experimentally measured the evolution of mean particle size, the number density, the volume fraction of Laves-phase precipitates, the partition coefficients of W and Mo in the matrix, as well as the change of hardness. Its main conclusions were: 1) Laves-phase nucleates and grows rapidly on grain boundaries and lath boundaries within the first 1500 h of aging time; 2) The two stages characteristics and kinetics of Laves-phase nucleation and growth which were determined experimentally; 3) The coarsening of Laves-phase is much faster than that of M23C6 carbides; 4) The precipitation of Laves-phase produces a pronounced matrix depletion of W and Mo atoms; and 5) The precipitated Laves-phase gives rise to weaker precipitation strengthening in comparison with M23C6 carbides, and causes the loss of hardness due to the depletion of Mo and W from the solid solution. This paper contributes to the knowledge of kinetics of Laves-phase precipitation and coarsening, providing the essential information for comparative investigation of creep damage mechanisms. This paper also contributes to the understanding the creep damage broadly.
