Influence of the synthesis parameters on the physico-chemical and catalytic properties of cerium oxide for application in the synthesis of diethyl carbonate

•Synthesis of cerium (IV) oxide by precipitation method.•Influence of synthesis time, calcination temperature, mode of stirring and solution pH on properties.•Characterization by XRD, SEM, TEM, nitrogen physisorption, XPS, FTIR.•Catalytic performance diethyl carbonate synthesis from ethanol and CO2.

Synthesis of cerium (IV) oxide by means of room temperature precipitation method was carried out. The effect of preparation variables such as synthesis time, calcination temperature and pH of the solution on resulting CeO2 properties was discussed. Moreover, the comparison of CeO2 samples prepared in a static and rotation mode of synthesis is presented. The solid catalysts were characterized by means of X-ray powder diffraction, scanning electron microscopy, transmission electron microscope, nitrogen physisorption, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy using pyridine as a probe molecule and temperature programmed desorption of CO2. Significant variations in physico-chemical properties of CeO2 by varying the preparation conditions were observed. Furthermore, the catalytic performances of CeO2 catalysts were compared in the synthesis of diethyl carbonate starting from ethanol and CO2 using butylene oxide as a dehydrating agent. The dependence of CeO2 properties on its catalytic activity is evaluated in detail.