| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1522658 | Materials Chemistry and Physics | 2013 | 8 Pages |
•EFE is a good eco-friendly inhibitor for the corrosion of carbon steel in 1 M HCl.•EFE acts as mixed-type inhibitor in 1 M HCl medium.•Weight loss, ac impedance and polarization methods are in reasonable agreement.•The adsorption of EFE is well described by the Langmuir adsorption isotherm.
Euphorbia falcata L. extract (EFE) was investigated as eco-friendly corrosion inhibitor of carbon steel in 1 M HCl using gravimetric, ac impedance, polarization and scanning electron microscopy (SEM) techniques. The experimental results show that EFE is good corrosion inhibitor and the protection efficiency is increased with the EEF concentration. The results obtained from weight loss and ac impedance studies were in reasonable agreement. Impedance experimental data revealed a frequency distribution of the capacitance, simulated as constant phase element. Polarization curves indicated that EFE is a mixed inhibitor. The corrosion inhibition was assumed to occur via adsorption of EFE molecules on the metal surface. The adsorption of the E. falcata extract was well described by the Langmuir adsorption isotherm. The calculated ΔGadso value showed that the corrosion inhibition of the carbon steel in 1 M HCl is mainly controlled by a physisorption process.
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