Article ID Journal Published Year Pages File Type
1522864 Materials Chemistry and Physics 2013 9 Pages PDF
Abstract

•The Cu2O/SnO2/graphene photocatalyst was prepared by a simple wet-chemical method.•Photocatalytic activity of the samples was studied for pendimethalin degradation.•CSG and SG exhibited excellent photocatalytic activities under visible-light.•A mechanism for highly efficient pendimethalin degradation by samples was proposed.

The Cu2O/SnO2/graphene (CSG) and SnO2/graphene (SG) nanocomposite photocatalysts were prepared by simple sol-gel growth method, and characterized by Fourier transform infrared spectra (FTIR), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and Brunauer–Emmett–Teller (BET) measurements, respectively. The photocatalytic efficiency of catalysts were evaluated by degradation of pendimethalin under visible light irradiation (λ > 420 nm), which conformed that CSG and SG exhibited better photocatalytic activity than SnO2 or graphene alone. An effort has been made to correlate the photoelectro-chemical behavior of these samples to the rate of photocatalytic degradation of pendimethalin.The results demonstrated that the cuprous oxide addition into SG materials could greatly improve the photoelectric activity. The mechanism of photocatalytic reaction is proposed based on the energy band theory and experimental results. The CSG catalyst with higher photocatalytic activity may have great potential in various fields.

Graphical abstractThe Cu2O/SnO2/graphene (CSG) nanocomposite photocatalyst has been prepared by a simple wet-chemical method. The CSG nanocomposite showed excellent photocatalytic activity under the visible-light for degradation of pendimethalin.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Materials Science Electronic, Optical and Magnetic Materials
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