Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1523354 | Materials Chemistry and Physics | 2013 | 4 Pages |
A convenient and efficient preparation method for separation graphene oxide with well-defined size distribution is developed using a centrifugation technique. The graded profile of graphene oxide nanosheets with narrow size distribution is effectively controlled by varying the centrifugation speed. The results show that the oxygen content of graphene oxide is highly dependent on their size distribution. Graphene oxide nanosheet with large size shows a red-shift in UV–vis absorption spectra, compared to graphene oxide with small size. This phenomenon is interpretation by a density functional theory calculation. The present work will provide a simple method to prepare graphene oxide nanosheets with controllable size distribution and C/O ratio, which will be valuable for the functionalization of graphene-based hybrids and the fabrication of graphene nano-devices.
► Well-defined size distribution of graphene oxide is developed using a centrifugation technique. ► The oxygen content of GO is highly dependent on their size distributions. ► UV–vis absorption spectrum shows a shift upon the size distribution. ► This phenomenon is interpreted by a density functional theory calculation.