| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1524084 | Materials Chemistry and Physics | 2012 | 9 Pages |
Abstract
⺠Up to 10% of the Cu/In sites is replaced with Mn in CuInS2. ⺠Mn prefers the In site under In-poor conditions for low-Mn-content samples. ⺠The oxidation states of Cu+, Mn2+ and In3+ are established. ⺠CuInS2:Mn is paramagnetic with short-range antiferromagnetic interactions. ⺠The bond alternation and p-d hybridization decrease the bandgap by â¼0.1 eV.
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Authors
Jinlei Yao, Brent W. Rudyk, Carl D. Brunetta, Kathyrn B. Knorr, Heather A. Figore, Arthur Mar, Jennifer A. Aitken,