Article ID Journal Published Year Pages File Type
1524451 Materials Chemistry and Physics 2010 6 Pages PDF
Abstract

Sr3Al2O6:Ce3+ phosphors were synthesized by a solid-state reaction method under mild reducing atmosphere of activated carbon. The effects of H3BO3 flux on the luminescence intensity and the optimum concentration of Ce3+ for luminescence property have been investigated. The effect of a small amount of charge compensators like Li+, Na+, K+ and Rb+ on Sr3Al2O6:Ce3+ phosphor has also been studied. Sr3Al2O6:Ce3+, R+(R = Li, Na, K and Rb) exhibit superior blue emission around 460 nm to Sr3Al2O6:Ce3+ and can be effectively excited by 395 nm light, which implies that efficient charge compensation can promote the luminescence of Ce3+ in Sr3Al2O6. The Sr3Al2O6:Ce3+, R+ (R = Li, Na, K and Rb) have potential application as a blue phosphor for n-UV chip excited white LEDs.

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Physical Sciences and Engineering Materials Science Electronic, Optical and Magnetic Materials
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