Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1526231 | Materials Chemistry and Physics | 2009 | 5 Pages |
Abstract
Pt-CeO2/C catalysts were synthesized by a one-step microwave polyol process and compared with Pt/C (E-TEK) catalyst in terms of the electrochemical activity for methanol oxidation using the cyclic voltammetry and chronoamperometry. The results demonstrated that Pt-CeO2/C catalysts exhibited lower onset potential, higher current peak and better stability for methanol electrooxidation than Pt/C (E-TEK) catalyst. The effect of ceria on the catalytic activity was investigated by electrochemical measurements and the highest electrochemical activity was obtained at the molar ratio of Pt to Ce by 2:1. The preliminary mechanism of the enhanced electrocatalytic performance for methanol oxidation was discussed.
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Authors
Jie Zhao, Weixiang Chen, Yifan Zheng,