Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1526362 | Materials Chemistry and Physics | 2009 | 7 Pages |
Abstract
Al current-collector with porous surface is coated with a conformal carbon (C) layer via a chemical vapor deposition process in CH4 at 600 °C. X-ray photoelectron spectroscopy analysis indicates that the coating process leads to the replacement of native aluminum oxide with a composite coating consisting of an Al4C3 interfacial layer and a C top layer. Activated C-based supercapacitors employing the resulting C-coated Al current-collectors have exhibited remarkably enhanced high-rate performance, and the enhancement can be attributed to two accounts. Firstly, the current-collector/active-layer interface resistance is reduced due to removal of the insulating oxide layer and improved adhesion of the active-layer on the current-collector. Secondly, the presence of the conducting C layer shortens the effective current conduction distance from the solid-electrolyte interface to the current-collector, leading to reduced charge-transfer resistance within the active-layer. Combining the C-coated Al current-collector with a C fiber active-layer that contains a large mesoporous pore volume (0.4 cm3 gâ1) has resulted in high-performance supercapacitors that exhibit, for instance, a cell specific energy of 18 Wh Kgâ1 at 25 °C or 7 Wh Kgâ1 at â10 °C under a cell specific power of 25 KW Kgâ1.
Keywords
Related Topics
Physical Sciences and Engineering
Materials Science
Electronic, Optical and Magnetic Materials
Authors
Hsien-Chang Wu, Yen-Po Lin, Eric Lee, Wen-Ting Lin, Jui-Kai Hu, Hung-Chang Chen, Nae-Lih Wu,