Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1526425 | Materials Chemistry and Physics | 2008 | 5 Pages |
Abstract
A novel route for the synthesis of a porous, gas-permeable carbon thin film produced from a metal carbide layer was developed. The active carbon layer, known as carbide-derived carbon, was synthesized by chlorination at 350 °C of a TiC thin film deposited onto a macroporous ceramic substrate by a magnetron sputtering technique. The resulting carbon layer was ∼500 nm in thickness with an amorphous carbon structure. Nitrogen permeability values of 67 Barrer are comparable to microporous polymer-derived carbon and advanced ceramic membranes.
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Authors
Elizabeth N. Hoffman, Gleb Yushin, Bogdan G. Wendler, Michel W. Barsoum, Yury Gogotsi,