Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1526951 | Materials Chemistry and Physics | 2008 | 5 Pages |
Abstract
Lead-free (Bi0.5Na0.5)1+xTiO3 ceramics (x = −0.02, −0.01, −0.005, 0, 0.005 and 0.01) were prepared by ordinary sintering. The effect of A-site stoichiometry on the densification, microstructure, dielectric properties, high-temperature impedances, and piezoelectric properties was explored. It was found that the high conductivity of (Bi0.5Na0.5)TiO3 (BNT) ceramics should be mainly attributed to the formation of A-site cation vacancies during sintering. Improved physical and electrical properties can be achieved in the sample with A-site cation excess. The control of the stoichiometry proves to be an effective way to improve BNT ceramics for possible application.
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Authors
Ruzhong Zuo, Shi Su, Yang Wu, Jian Fu, Min Wang, Longtu Li,