Article ID Journal Published Year Pages File Type
1526951 Materials Chemistry and Physics 2008 5 Pages PDF
Abstract

Lead-free (Bi0.5Na0.5)1+xTiO3 ceramics (x = −0.02, −0.01, −0.005, 0, 0.005 and 0.01) were prepared by ordinary sintering. The effect of A-site stoichiometry on the densification, microstructure, dielectric properties, high-temperature impedances, and piezoelectric properties was explored. It was found that the high conductivity of (Bi0.5Na0.5)TiO3 (BNT) ceramics should be mainly attributed to the formation of A-site cation vacancies during sintering. Improved physical and electrical properties can be achieved in the sample with A-site cation excess. The control of the stoichiometry proves to be an effective way to improve BNT ceramics for possible application.

Related Topics
Physical Sciences and Engineering Materials Science Electronic, Optical and Magnetic Materials
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