Article ID Journal Published Year Pages File Type
1527894 Materials Chemistry and Physics 2006 6 Pages PDF
Abstract

CdS nanocrystals with an average width of about 6 nm and narrow size distribution were synthesized in aqueous solution of pepsin at room temperature. The obtained CdS nanocrystals were characterized by transmission electron microscopy (TEM), X-ray powder diffraction (XRD) and thermogravimetric analysis (TGA). The quantum-confined effect of the CdS nanocrystals is confirmed by the ultraviolet–visible (UV–vis) and photoluminescence (PL) spectrum. The results indicate that the pepsin not only induce the nucleation, but inhibit the further growth of CdS nanocrystals. The effect of Cd2+ on pepsin and the change of pepsin conformation were studied through Fourier transform infrared (FTIR) spectroscopy. The possible mechanism of CdS nanocrystals growth in the pepsin solution was also discussed.

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Physical Sciences and Engineering Materials Science Electronic, Optical and Magnetic Materials
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