| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1528941 | Materials Science and Engineering: B | 2013 | 5 Pages |
•The Sr0.6(BiNa)0.2Bi2Nb2O9 ceramic by (LiCe) modification with the charge neutrality was synthesized by the solid state reaction method.•The Curie temperature and piezoelectric coefficient were found to be Tc ∼590 °C and d33 ∼32 pC/N, respectively.•The mechanism of piezoelectric activities improved by (LiCe) modification was discussed.
Aurivillius-type ceramics, Sr0.6−x(LiCe)x/2.5(BiNa)0.2Bi2Nb2O9(SLCBNBNO) with the charge neutrality, were synthesized by using conventional solid-state processing. Phase analysis was performed by X-ray diffraction analyses (XRD) and Raman spectroscopy. Microstructural morphology was assessed by the scanning electron microscopy (SEM). Structural, dielectric, piezoelectric, ferroelectric, and electromechanical properties of the SLCBNBNO ceramics were investigated. Piezoelectric properties were significantly enhanced compared to Sr0.6(BiNa)0.2Bi2Nb2O9 (SBNBN) ceramic and the maximum of piezoelectric coefficient d33 of the SBNBN-LC6 ceramic was 32 pC/N with higher Curie temperature (Tc ∼590 °C). In addition, mechanisms for the piezoelectric properties enhanced of the SBNBN-based ceramics were discussed.
Graphical abstractThe oxygen vacancies were confirmed by the left figure. The role of oxygen vacancy on piezoelectric activities was obtained by comparing to the varieties of oxygen vacancy concentration and piezoelectric coefficient with (LiCe) modification.Figure optionsDownload full-size imageDownload as PowerPoint slide
