Article ID Journal Published Year Pages File Type
1531982 Materials Science and Engineering: B 2006 4 Pages PDF
Abstract

Films of mixed zirconia and yttria were deposited electrochemically on stainless steel OC4004 from non-aqueous electrolytes based on ethyl alcohol, ZrCl4 and YCl3·6H2O. The film compositions were determined by X-ray photoelectron spectroscopy (XPS). After annealing of the layers, mixed oxides were formed. The changes in the valence-band (VB) below the Fermi level were studied on films with different Y/Zr ratios. SEM study of the electrodeposited layers showed them to be consisting of spherical agglomerates with sizes ranging from 0.1 to 0.5 μm.

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Physical Sciences and Engineering Materials Science Electronic, Optical and Magnetic Materials
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