Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1531982 | Materials Science and Engineering: B | 2006 | 4 Pages |
Abstract
Films of mixed zirconia and yttria were deposited electrochemically on stainless steel OC4004 from non-aqueous electrolytes based on ethyl alcohol, ZrCl4 and YCl3·6H2O. The film compositions were determined by X-ray photoelectron spectroscopy (XPS). After annealing of the layers, mixed oxides were formed. The changes in the valence-band (VB) below the Fermi level were studied on films with different Y/Zr ratios. SEM study of the electrodeposited layers showed them to be consisting of spherical agglomerates with sizes ranging from 0.1 to 0.5 μm.
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Authors
Ts. Marinova, A. Tsanev, D. Stoychev,