| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1544278 | Physica E: Low-dimensional Systems and Nanostructures | 2014 | 5 Pages |
•GO and reduced—GO have been synthesized by standard chemical method.•Both the oxides exhibit hysteresis and weak superparamagnetic behaviours at RT.•Superparamagnetism in these oxides is attributed to the presence of single domains.•Hysteresis is due to defect induced moments coupled by ferromagnetic interaction.
Graphite oxide (GO) and reduced graphene oxide (RGO) have been prepared using standard chemical methods. The formations of the oxides are characterized by X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) studies. Both the oxides exhibit weak superparamagnetism and hysteresis for the first time at room temperature. Magnetic moment for RGO is comparatively smaller than that of GO sample. The superparamagnetism in these oxides is attributed to the presence of single domains, each domain being cluster of defect induced magnetic moments coupled by ferromagnetic interaction. Apart from these single domain clusters there are other defect induced moments coupled by ferromagnetic interaction which show ferromagnetism and hysteresis.
Graphical abstractXRD, Magnetic moment Vs Field and FC and ZFC cures for RGO.Figure optionsDownload full-size imageDownload as PowerPoint slide
