Article ID Journal Published Year Pages File Type
1546572 Physica E: Low-dimensional Systems and Nanostructures 2008 5 Pages PDF
Abstract
The variation of magnetic susceptibility and heat capacity with temperature for the bimetallic nickel Ni(II)-copper Cu(II) cyclo-tetrametaphosphates (CuNiP4O12) has been examined. The complex has a structure of quasi-one-dimensional alternate spins chains of Ni(II) and Cu(II) that exhibits a three-dimensional magnetic ordering at approximately 13.5 K. The compound is characterized by a ferromagnetic intrachain constant JF=4.05 K, with a significant effect of single ion anisotropy D=9.70 K. The chains are weakly coupled antiferromagnetically with an interchain exchange constant of 2zAFJAF=−1.125 K.
Related Topics
Physical Sciences and Engineering Materials Science Electronic, Optical and Magnetic Materials
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