Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1550343 | Solar Energy | 2013 | 5 Pages |
•Coatings exhibit sunlight-activated self-cleaning and hydrophilic characteristics.•Self-cleaning coating on glass with enhanced transparency (up to 91%) to visible light over uncoated glass (90%).•Photoactive self-cleaning coatings deposited on surfaces other than glass.
A novel coating on soda-lime glass provided both self-cleaning properties, when exposed to sunlight, and high optical transparency (up to 91%). This coating was obtained from a dispersion of titanium dioxide nanocrystals in an aqueous hydrochloric acid solution of aluminum triisopropoxide. Applying this suspension to the glass substrate, and then heating 400 °C, resulted in a coating remaining on the glass surface. Interestingly, the transmission of light through the coated glass is slightly increased by circa 1–2% in the visible region (400–850 nm). The alumina/titanium dioxide coated glass exhibits photocatalytic activity on exposure to ultraviolat light (255 and 366 nm) in a laboratory setting and when placed in natural sunlight. A preliminary field test was conducted where samples of uncoated glass and alumina/titanium dioxide coated glass where placed outdoor side-by-side for two months. Uncoated glass samples became soiled resulting in a decreased transparency to circa 73–80%T at 580 nm (90%T at 580 nm when clean). In contrast the coated glass samples decreased only slightly to circa 90%T at 580 nm (91%T at 580 nm when clean). Substrates other than soda lime glass were also coated with a film of alumina/titanium dioxide without adversely affecting the properties of the substrate while providing photocatalytic activity.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide