Article ID Journal Published Year Pages File Type
1550837 Solar Energy 2012 9 Pages PDF
Abstract

Polyurethane polymers (PUs) have been synthesized as solid–solid phase change materials for thermal energy storage using three different kinds of diisocyanate molecules and polyethylene glycols (PEGs) at three different molecular weights. PEGs and their derivatives are usually used as phase change units in polymeric solid–solid phase change materials due to the hydroxyl functional groups. 1000, 6000, and 10,000 g/mol number average molecular weight PEGs are used as working element as hexamethylene, isophorone, and toluene diisocyanates are used as hard segment at the backbone. The effects of molecular weight of PEG and type of diisocyanate on the thermal energy storage properties have been discussed. Only two of the produced polymers show solid–liquid phase change as the rest show solid–solid phase transitions. The produced PUs with a solid–solid phase transitions have potential to be used in thermal energy storage systems.

► PU materials with solid–solid phase changing property were produced. ► Potential of materials for passive solar thermal energy storage was proved. ► Effect of ingredients used for PUs synthesis was accounted for energy storage.

Related Topics
Physical Sciences and Engineering Energy Renewable Energy, Sustainability and the Environment
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