Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1553868 | Superlattices and Microstructures | 2013 | 9 Pages |
Lithium ions were implanted at low energies (40 and 50 keV) and at a dosage of 5 × 1013 ions/cm2 over 〈0 0 2〉 ZnO thin films that had been deposited by pulsed laser deposition. The implanted samples were subsequently treated by rapid thermal annealing at 750 °C. Scanning electron microscopy images revealed improved grain formation for the implanted samples. However, a presence of microvoids was also observed in these samples; the amount of microvoids tended to increase on high-temperature annealing. Dominant donor-bound-exciton peaks is observed in all the samples along with some defect related to the exciton bound peaks although with a lesser intensity compared to as-deposited sample.
► Lithium-implantation performed on ZnO films to try to achieve p-type doping. ► Increase in carrier concentration for the implanted samples. ► Dominant donor-bound exciton peak for the samples, depict n-type conductivity. ► Presence of exciton bound defect peak due to implantation. ► No acceptor peak was visible in the PL spectra.