Enhanced Fracture Toughness of Pressureless-sintered SiC Ceramics by Addition of Graphene

To enhance the fracture toughness of pressureless-sintered SiC ceramic, graphene was introduced as an additive. The effects of graphene contents on the fracture toughness, bending strength, micro-hardness, phase compositions, and microstructure evolutions of the SiC ceramics were investigated in detail by scanning electron microscopy, energy dispersive X-ray spectroscopy, and metallographic microscopy. The fracture toughness, bending strength and micro-hardness increased initially, and then decreased with the graphene content increasing from 0 to 5.0 wt%. The highest fracture toughness of 5.65 MPa m1/2 was obtained for sample with 1.0 wt% graphene sintered at 2130 °C for 1 h in Ar, which was about 22.6% higher than that of SiC sample without graphene. In addition, the highest bending strength and micro-hardness of 434.14 MPa and 29.21 GPa corresponded to the SiC samples with graphene content of 0.5 wt% and 2.0 wt%, respectively.