Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1555812 | Journal of Materials Science & Technology | 2015 | 7 Pages |
Abstract
Nickel coatings with different microstructures were synthesized by pulse jet electrodeposition technique. Their morphology and microstructure were investigated by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The corrosion property of the coatings was studied by using polarization, electrochemical impedance spectroscopy (EIS), potential of zero free charge (PZFC) measurements and Mott–Schottky (M–S) relationship. The results showed that the coating with grain size of 50 nm possessed higher corrosion resistance than that with grain size of 10 nm. This abnormal behavior may be related to the existence of nanoscale twins in the coatings and the lower concentration of acceptor in the passive films.
Related Topics
Physical Sciences and Engineering
Materials Science
Materials Chemistry
Authors
Guozhe Meng, Yang Li, Yawei Shao, Tao Zhang, Yanqiu Wang, Fuhui Wang, Xuequn Cheng, Chaofang Dong, Xiaogang Li,