Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1558228 | New Carbon Materials | 2016 | 8 Pages |
Abstract
Rod-type ordered mesoporous carbons were synthesized by the direct carbonization of sulfuric-acid-treated silica/triblock copolymer composites, followed by etching the silica with a HF solution. The morphologies, microstructures and pore structures of the mesoporous carbons were investigated by scanning electron microscopy, high resolution transmission electron microscopy, X-ray diffraction and nitrogen sorption. Their electrochemical performance as electrodes for supercapacitors was investigated by impedance spectroscopy and charge/discharge tests. It was found that the rod length of the mesoporous carbons can be changed from one to tens of micrometers by changing the synthesis parameters. The sample with the longest rod length has the highest specific capacitance. The sample with two pore sizes has the highest capacitance retention ratio of 92% at a high current density of 2 A/g.
Related Topics
Physical Sciences and Engineering
Materials Science
Materials Chemistry
Authors
Na Liu, Lu-qiang Yu, Xiao-hong Chen, Li-fang Liao, Ji-sheng Zhou, Zao-kun Ma, Huai-he Song,