Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1558238 | New Carbon Materials | 2016 | 6 Pages |
Abstract
The effects of temperature on the oxidation behavior of the A3-3 matrix graphite (MG) in the temperature range 798-973 K in air with a flow rate of 100 ml/min to burn-offs of 10-15 wt%, were investigated by a home-made thermo-gravimetric experimental setup. The oxidation rate (OR) increases significantly with the temperature. The OR at 973 K is over 70 times faster than at 798 K. The oxidation kinetics of A3-3 MG in air at temperatures up to 973 K is in the reaction control regime, where the activation energy is 176 kJ/mol and the Arrhenius equation could be described as: OR=2.9673×108·exp(-21124.8/T) wt%/min. The relatively lower activation energy of MG than that of structural nuclear graphite indicates that MG is more easily oxidized.
Keywords
Related Topics
Physical Sciences and Engineering
Materials Science
Materials Chemistry
Authors
Xiang-wen Zhou, Zhen-ming Lu, Xin-nan Li, Jie Zhang, Bing Liu, Ya-ping Tang,