Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1559413 | Calphad | 2006 | 6 Pages |
Abstract
The selected pseudobinary, isothermal and isoactivity sections of the Bi2O3-SrO-MnOx phase diagram are constructed from the calculated phase equilibria. The starting point for the thermodynamic analysis were the assessments of the respective pseudobinary systems Bi2O3-SrO, Bi2O3-MnOx and SrO-MnOx. The only quaternary solid phase-the perovskite solid solution-is described in terms of the point defect model [ Bi3+1âxSr2+x] [ Mn3+1âx+2δ Mn4+xâ2δ] [O2â1âδ/3 V aδ/3]3. The quaternary liquid is approximated by a phenomenological model using the liquid species Mn, MnO, MnO1.5, SrO, and BiO1.5 with only binary Redlich-Kister coefficients. The ab initio electronic structure calculations of cohesive energies are employed to evaluate the enthalpies of formation of some stoichiometric phases.
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Physical Sciences and Engineering
Materials Science
Materials Science (General)
Authors
D. Sedmidubský, J. Leitner, O. Beneš,