Article ID Journal Published Year Pages File Type
156163 Chemical Engineering Science 2011 12 Pages PDF
Abstract

The motion of a solid spherical particle entrained in a Poiseuille flow between parallel plane walls has various applications to separation methods, like field-flow fractionation and hydrodynamic chromatography. Various handy formulae are presented here to describe the particle motion, with these applications in mind. Based on the assumption of a low Reynolds number, the multipole expansion method coupled to a Cartesian representation is applied to provide accurate results for various friction factors in the motion of a solid spherical particle embedded in a viscous fluid between parallel planes. Accurate results for the velocity of a freely moving solid spherical particle are then obtained. These data are fitted so as to obtain handy formulae, providing e.g. the velocity of the freely moving sphere with a 1% error. For cases where the interaction with a single wall is sufficient, simpler fitting formulae are proposed, based on earlier results using the bispherical coordinates method. It appears that the formulae considering only the interaction with a nearest wall are applicable for a surprisingly wide range of particle positions and channel widths. As an example of application, it is shown how in hydrodynamic chromatography earlier models ignoring the particle-wall hydrodynamic interactions fail to predict the proper choice of channel width for a selective separation. The presented formulae may also be used for modeling the transport of macromolecular or colloidal objects in microfluidic systems.

► Accurate calculations of the sphere velocity take both walls into account. ► Precise fitting formulae are obtained from these results. ► Simpler fitting formulae considering the nearest wall have a wide range of validity. ► Application to separation techniques shows important hydrodynamic wall effects. ► A large size selectivity regime appears for particle sizes close to channel thickness.

Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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