Article ID Journal Published Year Pages File Type
1564523 Computational Materials Science 2006 5 Pages PDF
Abstract
Ion exchanger is considered as the phase space being Gibbs canonical assembly. It is shown, that the canonical energy distribution results in a linear dependence of the differential free energy of ion exchange on the molar fraction of counterions in the ion exchanger phase in binary or multicomponent systems. A method for calculating of the phase composition of an ion exchanger at equilibrium with a multicomponent solution of electrolytes was proposed and tested for many experimental model systems.
Related Topics
Physical Sciences and Engineering Engineering Computational Mechanics
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