Multilayered sandwich-like architecture containing large-scale faceted Al–Cu–Fe quasicrystal grains

•A multilayered sandwich-like structure is produced by a facile method.•Each layer is covered by large-scale faceted Al–Cu–Fe quasicrystals.•There are channels between the adjacent Al–Cu–Fe layers.

Faceted quasicrystals are structurally special compared with traditional crystals. Although the application of faceted quasicrystals has been expected, wide-scale application has not occurred owing to the limited exposure of the facets. Using a facile method of heat treatment, we synthesize a multilayered sandwich-like structure with each layer composed of large-scale pentagonal-dodecahedra of Al–Cu–Fe quasicrystals. Moreover, there are channels between the adjacent Al–Cu–Fe layers that serve to increase the exposure of the facets of quasicrystals. Scanning electron microscopy, transmission electron microscopy, and X-ray diffraction are used to characterize the multilayered architecture, and the generation mechanisms of this special structure are also discussed.

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