Experimental characterization and population balance modelling of the dense silica suspensions aggregation process

The experiments were performed in a batch agitated vessel. The evolution of the particle size distributions versus time during the process of aggregation was particularly followed on-line by acoustic spectroscopy in dense conditions. Samples were also analyzed after an appropriate dilution by laser diffraction. The results show the different stages of the silica aggregation process whose kinetic rates depend either on physico-chemical parameters or on hydrodynamic conditions. Then, the study is completed by a numerical study based on the population balance approach. By the fixed pivot technique of Kumar and Ramkrishna [1996. On the solution of population balance equations by discretization-I. A fixed pivot technique. Chemical Engineering Science 51 (8), 1311-1332], the hypothesis on the mechanisms of the aggregation and breakage processes were justified. Finally, it allows a better understanding of the mechanisms of the aggregation process under flowing conditions.