Article ID Journal Published Year Pages File Type
1585125 Materials Science and Engineering: A 2006 9 Pages PDF
Abstract

Thermal shock cycling behaviors of D-gun sprayed TBCs with a hollow spherical ZrO2–8Y2O3 (HSP-YSZ) top coat and NiCrAlY bond coat on directionally solidified Ni-base superalloys DZ125 were investigated at high temperature (1100 °C) ↔ room temperature (RT) repeatedly by water quenching. Scanning electron microscopy (SEM) was used to characterize the coating microstructure and failure morphology. The results showed that failure of the D-gun sprayed TBC starts with crack initiation along the splats boundary in the ceramic top coat and the non-alumina oxides. The cracks propagate and coalesce with the increasing thermal cycling. The extensive cracking of the rapidly formed non-alumina oxides, resulting from the depletion of aluminum in the bond coat, aids to delamination of the outer ceramic layer. The stress distributions in TGO layer at different thermal shock cycles was measured by luminescence spectroscopy to investigate the failure mechanism of TBC system.

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Physical Sciences and Engineering Materials Science Materials Science (General)
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