| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1591824 | Solid State Communications | 2014 | 5 Pages |
•The zero field cooled and field cooled curves indicate the presence of a spin-glass behavior (x>0.1x>0.1).•The maximum magnetic entropy change was found to decrease drastically with Fe amount.•A large relative cooling power (RCP) of 270 J/kg is found for x=0.05.
The effect of Fe on the microstructure, magnetic and magnetocaloric properties has been investigated in the La0.6Ca0.4Mn1−xFexO3 (0≤x≤0.20≤x≤0.2) manganite compounds. X-ray diffraction reveals that all the samples crystallize in a rhombohedral structure (space group R3¯c) and that the introduction of iron does not affect the lattice parameters and structural symmetry. With the increasing Fe content, the Curie temperature TCTC decreases from 275 K (x=0) to 75 K (x =0.2). Temperature dependences of the magnetization in both field cooled and zero field cooled modes show the coexistence of ferromagnetic and antiferromagnetic interactions for x≥0.1x≥0.1. The maximum entropy change ΔSMΔSM exhibits a decrease from 5.2 J/kg K for x=0 to 0.2 J/kg K for x=0.2 under an applied magnetic field change of 5 T. The highest relative cooling power was found to be equal to 270 J/kg for x=0.05, suggesting that La0.6Ca0.4Mn0.95Fe0.05O3 may be a suitable candidate for magnetic refrigeration.
