Article ID Journal Published Year Pages File Type
1594556 Solid State Communications 2010 4 Pages PDF
Abstract
A temperature dependent synchrotron X-ray powder diffraction study has been carried out on Na1/2Pr1/2TiO3 up to 850 °C. The compound shows orthorhombic (Pbnm) → orthorhombic (Ibmm) → tetragonal (I4/mcm) transitions at ∼150 °C, and ∼750 °C, respectively. An unusual volume expansion below 500 °C has been noticed in the Ibmm phase, suggesting the onset of another, yet unknown, physical phenomenon unrelated to the crystallographic changes below this temperature.
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Physical Sciences and Engineering Materials Science Materials Science (General)
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