| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1596365 | Solid State Communications | 2007 | 5 Pages |
Raman spectroscopy studies are reported for the RuSr2Eu1.5Ce0.5Cu2O10 (Ru-1222) compound at various temperatures of 300, 250, 200 and 90 K. Three distinct vibrational bands: the first at 110, 140, and 160 cm−1, the second at 295 and 347 cm−1, and third one at 651 cm−1 are seen in Raman spectra of the compound at room temperature. These bands are attached to the Cu atoms’ cc-direction, the Ru atoms’ ab -plane stretching and Ru atoms’ cc-direction anti-stretching modes. Below 200 K, an extra vibrational mode is also seen at 260 cm−1. Also, with a decrease in temperature, though the Cu vibrational modes remain intact, the Ru atoms’ ab-plane stretching (295 cm−1) and cc-direction anti-stretching (651 cm−1) modes shift gradually to higher wave number positions. The frequencies of modes at 260 and 651 cm−1 showed anomalous softening and line-width broadening below 100 K that corroborates well with the spin ordering seen in susceptibility studies. The studied compound is a ferromagnetic superconductor with magnetic ordering of the Ru spins at 200 K and superconductivity below 30 K. A magnetic and electrical transport characterization of the compound is also presented briefly.
