Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1596750 | Solid State Communications | 2006 | 5 Pages |
Pressure induced structural transition of yttrium hydride has been investigated using synchrotron radiation X-ray diffraction measurement up to 24 GPa at room temperature. A reversible hexagonal–fcc transition with a wide intermediate region from 11 to 20 GPa is confirmed, which is consistent with previously reported X-ray results. The diffraction patterns measured for the intermediate state are not interpreted in terms of a hexagonal–fcc coexisting state or as rare-earth structures with various metal-layer stacking sequences. The equation of state determined for the hexagonal–YH3 provides a bulk modulus B0 of 71.9 GPa, which is nearly half of the previously reported value, but is within the range of values reported for other rare-earth metal trihydrides with hexagonal structures.