Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1600750 | Intermetallics | 2011 | 8 Pages |
Abstract
The uranium Laves phase UFe2 was prepared by ultrafast cooling, which allows to incorporate excessive Fe of about 0.3 Fe/f.u. into the nanocrystalline Laves phase structure. 57Fe Mössbauer spectroscopy reveals that such Fe atoms occupy the U sites. Stronger magnetic hyperfine field points to larger Fe moments of such antistructure Fe. Higher Fe excess leads to its segregation in the form of α-Fe. The Curie temperature of the UFe2+x phase increases to the limit value 230–240 K.
Keywords
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
L. Havela, K. Miliyanchuk, A.P. Gonçalves, J.C. Waerenborgh, L.C.J. Pereira, P. Gaczynski, E.B. Lopes, J. Pešička,