Article ID Journal Published Year Pages File Type
1601617 Intermetallics 2007 7 Pages PDF
Abstract

The phase formation and crystallization kinetics during the thermal treatment of amorphous Zr60Al15Ni25 alloy were investigated by differential scanning calorimetry (DSC) and X-ray diffraction (XRD). By lowering the isothermal annealing temperatures, it is revealed that the crystallization of the amorphous Zr60Al15Ni25 alloy consists of a primary transformation followed by a polymorphic transformation, corresponding to the precipitations of hexagonal Zr6Al2Ni and the Zr5AlNi4 with a U3Si2-typed superstructure. The primary phase being Zr6Al2Ni rather than Zr5AlNi4 in the crystallization is because the latter has a complex structure and its formation requires the diffusion of Al and Zr atoms on a large scale.

Related Topics
Physical Sciences and Engineering Materials Science Metals and Alloys
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