Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1601617 | Intermetallics | 2007 | 7 Pages |
Abstract
The phase formation and crystallization kinetics during the thermal treatment of amorphous Zr60Al15Ni25 alloy were investigated by differential scanning calorimetry (DSC) and X-ray diffraction (XRD). By lowering the isothermal annealing temperatures, it is revealed that the crystallization of the amorphous Zr60Al15Ni25 alloy consists of a primary transformation followed by a polymorphic transformation, corresponding to the precipitations of hexagonal Zr6Al2Ni and the Zr5AlNi4 with a U3Si2-typed superstructure. The primary phase being Zr6Al2Ni rather than Zr5AlNi4 in the crystallization is because the latter has a complex structure and its formation requires the diffusion of Al and Zr atoms on a large scale.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
J.F. Li, Z.H. Huang, Y.H. Zhou,