Suspension polymerisation of methyl methacrylate using sodium polymethacrylate as a suspending agent

Aqueous solutions of sodium polymethacrylate (PMA-Na) are used as suspending agents for the suspension polymerisation of methyl methacrylate. These aqueous polyelectrolyte solutions are viscous and they show a non-Newtonian shear thinning behaviour. The Sauter mean drop diameter decreases with increasing continuous-phase viscosity, but increases with increasing stirring speed. The maximum drop sizes follow the same trends. The Sauter mean diameter also decreases, initially, for increasing hold-up, reaches a minimum, and then increases with increasing hold-up. Taylor's theory of viscous break-up seems to be suitable to describe the breakage of the droplets.