Article ID Journal Published Year Pages File Type
1603816 International Journal of Refractory Metals and Hard Materials 2012 5 Pages PDF
Abstract

The interdiffusion of HfC and TiC during hot pressing was investigated using concentration profiles obtained via EDS in a SEM. The results were interpreted using the Boltzmann–Matano method and the integrals and derivatives were determined via numerical means. The microstructural evolution of two materials with different HfC/TiC is then explained in terms of the rate of material movement.

► Sintering solid HfC and TiC pellets results in diffusion of the transition metals into each other. ► The rate of diffusion of TiC is faster than HfC. ► The Boltzmann–Matano is used to determine the Matano interface and the diffusion coefficient as a function of concentration.

Related Topics
Physical Sciences and Engineering Materials Science Metals and Alloys
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