Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1604965 | Journal of Alloys and Compounds | 2017 | 12 Pages |
Abstract
Atom Probe Microscopy has been performed on a titanium-molybdenum microalloyed steel after simulation of thermomechanical processing. The results reveal the evolution of clustering and precipitation reactions at the austenite/ferrite interphase interface during isothermal heat treatments of durations ranging between 300 s and 100 h. Shorter isothermal ageing times led to extensive solute clustering at the austenite/ferrite interface, which remained free of precipitates. For ageing times beyond 3600 s, high number densities of interphase nano-precipitates were observed along with extensive solute clustering. Beyond 100 h, there was little evidence of solute clustering at these austenite/ferrite microstructural interfaces, which were instead dominated by a dispersion of coarser nano-precipitates. Both the clusters and nano-precipitates formed during isothermal ageing possessed a disc shape morphology and the growth has taken place in the through thickness direction of the disc without much change in the aspect ratio. The size of clusters and nano-precipitates increased from â¼2 nm after 300 s to â¼15 nm after 100 h of isothermal ageing at 650 °C. The solute clusters contain mainly C, Ti and Mo atoms, while the stoichiometry of the nano-precipitates approached that of MC carbide as their size increased beyond â¼4 nm. It is proposed that Mo controls the process of precipitate growth, resulting in a fine and uniform dispersion of nano-precipitates and a high level of tensile strength after just 300 s ageing at 650 °C. Interestingly, the peak strength was achieved during the very early stages of the precipitation process.
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Subrata Mukherjee, Ilana Timokhina, Chen Zhu, Simon P. Ringer, Peter D. Hodgson,