Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1607335 | Journal of Alloys and Compounds | 2016 | 6 Pages |
Abstract
Ta2O5 quantum dots were grown using simple vacuum thermal evaporation technique. The development of residual stress progresses with increasing dot size or film thickness. Residual stress effect on band gap of orthorhombic Ta2O5 quantum dots is studied. Both SAED and XRD confirm that the films thicker than 45Â nm become amorphous. The variation of residual stress with film thickness scales linearly very well with the varying band gap with film thickness. Stress free band gap (3.94Â eV) and pressure coefficient of band gap (âEg/âP)TÂ =Â â26.4Â meV/GPa) were determined from this study. Transformation from crystalline to amorphous phase in orthorhombic form of Ta2O5 has been determined to be at about 18Â GPa. Both crystalline to amorphous transition and pressure coefficient of band gap for orthorhombic Ta2O5 driven by residual stress have been determined for the first time in the literature.93
Keywords
Related Topics
Physical Sciences and Engineering
Materials Science
Metals and Alloys
Authors
Sahil Dhawan, Tanuj Dhawan, Agnikumar G. Vedeshwar,